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Date: 23-1-2022
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Date: 16-1-2022
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Markovnikov’s rule (restated)
In the addition of HX to an alkene, the more highly substituted carbocation is formed as the intermediate rather than the less highly substituted one. For example, addition of H+ to 2-methylpropene yields the intermediate tertiary carbocation rather than the alternative primary carbocation, and addition to 1-methylcyclohexene yields a tertiary cation rather than a secondary one. Why should this be?
q/ Predicting the Product of an Electrophilic Addition Reaction
What product would you expect from reaction of HCl with 1 ethylcyclopentene?
S t r a t e g y
When solving a problem that asks you to predict a reaction product, begin by looking at the functional group(s) in the reactants and deciding what kind of reaction is likely to occur. In the present instance, the reactant is an alkene that will probably undergo an electrophilic addition reaction with HCl. Next, recall what you know about electrophilic addition reactions to predict the product. You know that electrophilic addition reactions follow Markovnikov’s rule, so H1 will add to the double-bond carbon that has one alkyl group (C2 on the ring) and the Cl will add to the double-bond carbon that has two alkyl groups (C1 on the ring).
S o l u t i o n
The expected product is 1-chloro-1-ethylcyclopentane.
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