The Functional Group

With over twenty million known organic compounds in existence, it would be very challenging to memorize chemical reactions for each one. Fortunately, molecules with similar functional groups tend to undergo similar reactions. A functional group is defined as an atom or group of atoms within a molecule that has similar chemical properties whenever it appears in various compounds. Even if other parts of the molecule are quite different, certain functional groups tend to react in certain ways.

We've already looked at alkanes, but they are generally unreactive. We primarily use alkanes as a source of energy when they are combusted. While the majority of functional groups involve atoms other than carbon and hydrogen, we will also look at some that include only carbon and hydrogen. Some of the most common functional groups are presented in the following sections.

Organic molecules vary greatly in size and when focusing on functional groups, we want to direct our attention to the atoms involved in the functional group. As a result, the abbreviation R is used in some examples. The letter R is used in molecular structures to represent the “Rest of the molecule”. It consists of a group of carbon and hydrogen atoms of any size. It is used as an abbreviation since a group of carbon and hydrogen atoms does not affect the functionality of the compound. In some molecules, you will see R, R’, or R’’ which indicates that the R groups in the molecule can be different from one another. For example, R might be –CH₂CH₃ while R’ is –CH₂CH₂CH₂CH₃.

The structure of capsaicin, the compound responsible for the heat in peppers, incorporates several functional groups, labeled in the figure below and explained throughout this section and the following ones.

The table below summarizes the structures that will be discussed in this chapter:

Table1: Selected Organic Functional Groups