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Date: 28-8-2018
1023
Date: 13-10-2020
1025
Date: 5-9-2018
1037
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Variation of rates when you change the halogen
Reaction rates increase in the order HF - HCl - HBr - HI. Hydrogen fluoride reacts much more slowly than the other three, and is normally ignored in talking about these reactions. When the hydrogen halides react with alkenes, the hydrogen-halogen bond has to be broken. The bond strength falls as you go from HF to HI, and the hydrogen-fluorine bond is particularly strong. Because it is difficult to break the bond between the hydrogen and the fluorine, the addition of HF is bound to be slow.
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