Classification of Carbohydrates
Carbohydrates are the most abundant class of organic compounds found in living organisms. They originate as products of photosynthesis, an endothermic reductive condensation of carbon dioxide requiring light energy and the pigment chlorophyll.
nCO2+nH2O+Energy→CnH2nOn+nO2
As noted here, the formulas of many carbohydrates can be written as carbon hydrates, Cn(H2O)n , hence their name. The carbohydrates are a major source of metabolic energy, both for plants and for animals that depend on plants for food. Aside from the sugars and starches that meet this vital nutritional role, carbohydrates also serve as a structural material (cellulose), a component of the energy transport compound ATP/ADP, recognition sites on cell surfaces, and one of three essential components of DNA and RNA.
Carbohydrates are called saccharides or, if they are relatively small, sugars. Several classifications of carbohydrates have proven useful, and are outlined in the following table.
Complexity
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Simple Carbohydrates
monosaccharides
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Complex Carbohydrates
disaccharides, oligosaccharides
& polysaccharides
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Size
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Tetrose
C4 sugars
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Pentose
C5 sugars
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Hexose
C6 sugars
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Heptose
C7 sugars
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etc.
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C=O Function
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Aldose
sugars having an aldehyde function or an acetal equivalent.
Ketose
sugars having a ketone function or an acetal equivalent.
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Reactivity
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Reducing
sugars oxidized by Tollens' reagent (or Benedict's or Fehling's reagents).
Non-reducing
sugars not oxidized by Tollens' or other reagents.
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