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Date: 12-5-2016
4094
Date: 21-8-2016
2097
Date: 21-8-2016
3939
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A three membered ring has no rotational freedom whatsoever. A plane is defined by three points, so the three carbon atoms in cyclopropane are all constrained to lie in the same plane.
Furthermore, if you look at a model you will find that the neighboring C-H bonds (C-C bonds, too) are all held in eclipsed conformations.
Cyclopropane is always at maximum torsional strain. This strain can be illustrated in a line drawing of cyclopropane as shown from the side. In this oblique view, the dark lines mean that those sides of the ring are closer to you.
However, the ring isn't big enough to introduce any steric strain, which does not become a factor until we reach six membered rings. Until that point, rings are not flexible enough for two atoms to reach around and bump into each other.
The really big problem with cyclopropane is that the C-C-C bond angles are all too small.
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تفوقت في الاختبار على الجميع.. فاكهة "خارقة" في عالم التغذية
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أمين عام أوبك: النفط الخام والغاز الطبيعي "هبة من الله"
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قسم شؤون المعارف ينظم دورة عن آليات عمل الفهارس الفنية للموسوعات والكتب لملاكاته
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