Example 3
With arrows, illustrate the transfer of electrons to form calcium chloride from Ca atoms and Cl atoms.
Solution
A Ca atom has two valence electrons, while a Cl atom has seven electrons. A Cl atom needs only one more to complete its octet, while Ca atoms have two electrons to lose. Thus we need two Cl atoms to accept the two electrons from one Ca atom. The transfer process looks like this:

Key Takeaways
- The tendency to form species that have eight electrons in the valence shell is called the octet rule.
- The attraction of oppositely charged ions caused by electron transfer is called an ionic bond.
- The strength of ionic bonding depends on the magnitude of the charges and the sizes of the ions.
Exercises
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Comment on the possible formation of the K2+ ion. Why is its formation unlikely?
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Comment on the possible formation of the Cl2− ion. Why is its formation unlikely?
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How many electrons does a Ba atom have to lose to have a complete octet in its valence shell?
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How many electrons does a Pb atom have to lose to have a complete octet in its valence shell?
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How many electrons does an Se atom have to gain to have a complete octet in its valence shell?
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How many electrons does an N atom have to gain to have a complete octet in its valence shell?
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With arrows, illustrate the transfer of electrons to form potassium chloride from K atoms and Cl atoms.
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With arrows, illustrate the transfer of electrons to form magnesium sulfide from Mg atoms and S atoms.
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With arrows, illustrate the transfer of electrons to form scandium fluoride from Sc atoms and F atoms.
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With arrows, illustrate the transfer of electrons to form rubidium phosphide from Rb atoms and P atoms.
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Which ionic compound has the higher lattice energy—KI or MgO? Why?
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Which ionic compound has the higher lattice energy—KI or LiF? Why?
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Which ionic compound has the higher lattice energy—BaS or MgO? Why?
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Which ionic compound has the higher lattice energy—NaCl or NaI? Why?
Answers
1.
The K2+ ion is unlikely to form because the K+ ion already satisfies the octet rule and is rather stable.
3.
two
5.
two
7.
9.
11.
MgO because the ions have a higher magnitude charge
13.
MgO because the ions are smaller