Formal Charges

It is sometimes possible to write more than one Lewis structure for a substance that does not violate the octet rule, as we saw for CH₂O, but not every Lewis structure may be equally reasonable. In these situations, we can choose the most stable Lewis structure by considering the formal charge on the atoms, which is the difference between the number of valence electrons in the free atom and the number assigned to it in the Lewis electron structure. The formal charge is a way of computing the charge distribution within a Lewis structure; the sum of the formal charges on the atoms within a molecule or an ion must equal the overall charge on the molecule or ion. A formal charge does not represent a true charge on an atom in a covalent bond but is simply used to predict the most likely structure when a compound has more than one valid Lewis structure.

To calculate formal charges, we assign electrons in the molecule to individual atoms according to these rules:

• Nonbonding electrons are assigned to the atom on which they are located.
• Bonding electrons are divided equally between the bonded atoms.

For each atom, we then compute a formal charge:

To illustrate this method, let’s calculate the formal charge on the atoms in ammonia (NH₃) whose Lewis electron structure is as follows:

A neutral nitrogen atom has five valence electrons (it is in group 15). From its Lewis electron structure, the nitrogen atom in ammonia has one lone pair and shares three bonding pairs with hydrogen atoms, so nitrogen itself is assigned a total of five electrons [2 nonbonding e⁻ + (6 bonding e⁻/2)]. Substituting into Equation below we obtain

A neutral hydrogen atom has one valence electron. Each hydrogen atom in the molecule shares one pair of bonding electrons and is therefore assigned one electron [0 nonbonding e⁻ + (2 bonding e⁻/2)]. Using Equation above to calculate the formal charge on hydrogen, we obtain 

Typically, the structure with the most charges on the atoms closest to zero is the more stable Lewis structure. In cases where there are positive or negative formal charges on various atoms, stable structures generally have negative formal charges on the more electronegative atoms and positive formal charges on the less electronegative atoms. The next example further demonstrates how to calculate formal charges.

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مواد التبادل الأيوني Ion exchanger

ظاهرة التبادل الايوني Ion Exchange

تاريخ التبادل الايوني Ion Exchange History

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